Continuous process applied to degradation of triclosan and 2.8-dichlorodibenzene-p-dioxin.

This study describes the use of a prototype for the continuous photocatalytic reaction process using Fe/Nb2O5-immobilized catalyst for triclosan and 2.8-dichlorodibenzene-p-dioxin (2.8-DCDD)'s degradation. The experiments were carried out with different parameters and matrices in a steady state. In addition, photolysis and photocatalytic tests were performed. The results indicated that the generation of 2.8-DCDD was observed in matrices with Cl-. The Fe/Nb2O5-immobilized catalysts were efficient in the degradation of triclosan and 2.8-dichlorodibenzene-p-dioxin. However, 2.8-DCDD formation was not observed in the ultra-pure water matrix, which indicated influence of ions. The photocatalysis was more efficient than the photolysis when comparing both matrices and radiation. Even with a radiation oscillation, the solar process showed positive results.

Modeling, simulation, and analysis of a reactor system for the generation of white liquor of a pulp and paper industry

An industrial system for the production of white liquor of a pulp and paper industry, Klabin Paraná Papéis, formed by ten reactors was modeled, simulated, and analyzed. The developed model considered possible water losses by the evaporation and reaction, in addition to variations in the volumetric flow of lime mud across the reactors due to the composition variations. The model predictions agreed well with the process measurements at the plant and the results showed that the slaking reaction was nearly complete at the third causticizing reactor, while causticizing ends by the seventh reactor. Water loss due to slaking reaction and evaporation occurred more pronouncedly in the slaker reactor than in the final causticizing reactors; nevertheless, the lime mud flow remained nearly constant across the reactors.

Effect of water losses by evaporation and chemical reaction in an industrial slaker reactor

A dynamic model of the slaker reactor was developed and validated for Klabin Paraná Papéis causticizing system, responsable for white liquor generation used by the plant. The model considered water losses by evaporation and chemical reaction. The model showed a good agreement with the industrial plant measures of active alkali, total titratable alkali and temperature, without the need of adjustment of any parameter. The simulated results showed that the water consumption by the slaking reaction and evaporation exerted significant influence on the volumetric flow rate of limed liquor, which imposed a decrease of 4.6 percent in the amount of water in reactor outlet.

Foi desenvolvido e testado um modelo dinâmico do reator de apagamento do sistema de caustificação da Klabin Paraná Papéis, responsável pela geração do licor branco utilizado na planta. O modelo contempla perdas de água por evaporação e por reação química e apresentou boa concordância com dados industriais de álcali ativo, álcali total titulável e temperatura, sem a necessidade de ajuste de nenhum parâmetro. Os resultados obtidos a partir de simulações revelam que o consumo de água pela reação de apagamento, bem como pela evaporação, exercem uma influência significativa sobre a vazão volumétrica na saída do reator, impondo uma diminuição de 4,6 por cento sobre o teor de água na corrente de saída do reator em relação à alimentação.